The order of basic strength of aliphatic amines in the aqueous phase is based on the following factors:Steric factor: Alkyl group is larger than hydrogen atom that causes steric hindrance to attack of acid. As the number of alkyl group increases from primary to tertiary. The steric hindrance also increases in the same direction.Solvation of ions: when amines are dissolved in water, they form ...

(ch3)2nh hydrogen bonding

Polar "In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups Polar molecules interact through dipole-dipole intermolecular forces and hydrogen bonds. o Significant in large atoms/molecules o Larger surface area facilitates the formation of these induced dipoles o Present. com Blogger 37 1 25 tag. polarity and possibility for hydrogen bonding: #3 is nonpolar; #4 is polar but cannot form hydrogen bonds; #2 is polar, but its hydrogen bonds will be weaker than those in an alcohol; #5 is a secondary alcohol, so will form fewer hydrogen bonds than its primary isomer. Diff: 3. Section: 15.2

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(b) (CH3)2NH (e) H3C (c) MgBr2 (f) (CH3)3P 26 CHAPTER 1 | Structure and Bonding; Acids and Bases Problem 1.24 Show how the species in part (a) can act as Lewis bases in their reactions with HCl, and show how the species in part (b) can act as Lewis acids in their reaction with OH . (a) CH3CH2OH, (CH3)2NH, (CH3)3P (b) H3C , (CH3)3B, MgBr2 ...
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(ch3)2nh hydrogen bonding

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(ch3)2nh hydrogen bonding